Bis[O-propyl (4-ethoxyphenyl)dithiophosphonato-κ2 S,S′]nickel(II)
نویسندگان
چکیده
The title compound, [Ni(C11H16O2PS2)2], contains a four-coordinate Ni(II) cation with an idealized square-planar geometry. The metal atom is surrounded by two chelating isobidentate dithio-phospho-nate ligands in a trans or anti configuration, binding through the S-donor atoms.
منابع مشابه
Bis[O-methyl (4-ethoxyphenyl)dithiophosphonato-κ2 S,S′]nickel(II)
In the title compound, [Ni(C9H12O2PS2)2], the Ni(II) atom resides on an inversion center and is coordinated by four S atoms [Ni-S = 2.2328 (4) and 2.2455 (3) Å] in a distorted square-planar geometry [S-Ni-S = 88.443 (13) and 91.557 (13)°]. In the crystal, mol-ecules related by translation in [110] are linked into chains via weak C-H⋯O inter-actions. The crystal packing exhibits short inter-mole...
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The title compound, [Hg2(C11H16O2PS2)4], is a dinuclear complex with a distorted tetra-hedral geometry around each Hg(II) atom. Although the two Hg(II) atoms are surrounded by the same ligand, two different coordination modes are observed: one is chelating and the other bridging. The Hg-S bonds form two distinct pairs of long and short bonds. One pair includes both chelating and bridging Hg-S b...
متن کاملBis[O-propan-2-yl (4-ethoxyphenyl)dithiophosphonato-κ2 S,S′]nickel(II)
The title compound, [Ni(C11H16O2PS2)2], is a neutral four-coordinate mononuclear complex with a square-planar geometry. The complex lies on an inversion center. The metal atom is surrounded by two chelating isobidentate O-propan-2-yl (4-eth-oxy-phen-yl)dithio-phospho-nate ligands in a trans configuration binding through the S-donor atoms. The Ni-S bond lengths are 2.2328 (5) and 2.2369 (5) Å, a...
متن کاملBis[O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ2 S,S′]lead(II)
The title compound, [Pb(C11H16O2PS2)2], is a neutral four-coordinate mononuclear complex with a distorted square-pyramidal geometry of the PbS4 core. The apical Pb(II) atom of each pyramid is 1.33059 (3) Å above the basal S4 plane. The metal atom is surrounded by two chelating dithio-phospho-nate ligands binding through the S-donor atoms. The ligands are anisobidentate as the pyramid is compris...
متن کاملcatena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2 S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2 N:N′]
The Ni atom in the title linear supra-molecular polymer, [Ni(C(6)H(14)O(2)PS(2))(2)(C(12)H(10)N(4))](n), exists within a trans-N(2)S(4) octa-hedral donor set defined by two symmetrically coordinating dithio-phosphate ligands and pyridine N atoms derived from two bridging bis-(4-pyridylmethyl-ene)diazane ligands. The Ni atom lies on a centre of inversion and the bis-(4-pyridylmethyl-ene)diazane ...
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